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J. Semicond. > 2019, Volume 40?>?Issue 3?> 032802

ARTICLES

Numerical simulation of UV LEDs with GaN and BGaN single quantum well

Asma Belaid and Abdelkader Hamdoune

+ Author Affiliations

 Corresponding author: Asma Belaid, Email: belaidaasma@gmail.com

DOI: 10.1088/1674-4926/40/3/032802

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Abstract: The objective of this work is to simulate a single quantum well ultraviolet light emitting diode (LED) based on AlGaN/GaN/AlGaN and AlGaN/BGaN/AlGaN, by using TCAD Silvaco simulator. The first structure has a GaN quantum well taken between two layers, of n-AlGaN and p-AlGaN. The second one has a BGaN quantum well instead of GaN. We fix the concentration of the boron in BGaN to only 1% and we vary the thickness of GaN and BGaN quantum well layer from 7 to 20 nm, for the two structures. As results, we obtain respectively for GaN-LED and BGaN-LED, a maximum current of 0.52 and 0.27 mA, a maximum power spectral density of 1.935 and 6.7 W cm?1 eV?1, a maximum spontaneous emission of 3.34 × 1028 and 3.43 × 1028 s?1 cm?3 eV?1, and a maximum Light output power of 0.56 and 0.89 mW.

Key words: gallium nitride (GaN)aluminum gallium nitride (AlGaN)boron gallium nitride (BGaN)UV light emitting diode (LED)



[1]
Hamdoune A. Elaboration du nitrure de gallium, étude de ses propriétés et applications. Thesis of Doctorate, University of Abou-Bakr Belkaid, Tlemcen, Algeria, 2006
[2]
Nakamura S. III-V nitride based light-emitting devices. Solid State Communications, 1997. 102: 237 doi: 10.1016/S0038-1098(96)00722-3
[3]
Masui H, Nakamura S, DenBaars S P, et al. Nonpolar and semipolar III-nitride light-emitting diodes: achievements and challenges. IEEE Trans Electron Devices, 2010, 57: 88 doi: 10.1109/TED.2009.2033773
[4]
Hu H P, Zhou S J, Liu X T, et al. Effects of GaN/AlGaN/sputtered AlN nucleation layers on performance of GaN-based ultraviolet light-emitting diodes. J Scientific Reports, 2017, 7, 44627 doi: 10.1038/srep44627
[5]
Kneissl M, Kolbe T, Chua C, et al. Advances in group III-nitride-based deep UV light-emitting diode technology. J Semicond Sci Technol 2011, 26 , 014036 doi: 10.1088/0268-1242/26/1/014036
[6]
Kneissl M, Rass J. III nitride ultraviolet emitters. Springer Series in Materials Science 2016, 227, 1
[7]
Khan A, Balakrishnan K, Katona T. Ultraviolet light-emitting diodes based on group three nitrides. J Nat Photonics 2008, 2, 77 doi: 10.1038/nphoton.2007.293
[8]
Nakamura S, Krames M R. History of gallium-nitride-based light-emitting diodes for illumination. Proc IEEE, 2013, 101(10), 2211 doi: 10.1109/JPROC.2013.2274929
[9]
Verzellesi G , Saguatti D, Meneghini M, et al. Efficiency droop in InGaN/GaN blue light-emitting diodes: physic mechanisms remedies. J Appl Phys 2013, 114(7), 071101. doi: 10.1063/1.4816434
[10]
Yang W, Wang W, Lin Y, et al. Deposition of nonpolar mplane InGaN/GaN multiple quantum wells on LiGaO+(100) substrates. J Mater Chem C 2014, 2(5), 801 doi: 10.1039/C3TC31935K
[11]
Schubert M F, Xu J, Kim J K, et al. Polarization-matched GaInN/AlGaInN multi-quantum-well light-emitting diodes with reduced efficiency droop. Appl Phys Lett. 2008, 93(4), 041102. doi: 10.1063/1.2963029
[12]
Lin Z T, Wang H Y, Wang W L, et al. Employing low-temperature barriers to achieve strain-relaxed and high-performance GaN-based LEDs. J Opt Express, 2016, 24, 11886. doi: 10.1364/OE.24.011885
[13]
Hirayama H, Fujikawa S, Noguchi N, et al. 222–282 nm AlGaN and InAlGaN-based deep-UV LEDs fabricated on high-quality AlN on sapphire. J Phys Status Solidi A, 2009, 206, 1176 doi: 10.1002/pssa.v206:6
[14]
Takano T, Fujikawa S, Kondo Y, et al. Remarkable improvement in output power for an InAlGaN based ultraviolet LED by improving the crystalline quality of AlN/AlGaN templates. J Phys Status Solidi C, 2008, 5, 2102 doi: 10.1002/(ISSN)1610-1642
[15]
Lin Z T, Wang H T, Lin Y H, et al. Stress management on underlying GaN-based epitaxial films: A new vision for achieving high-performance LEDs on Si substrates. J Appl Phys, 2017, 122, 204503. doi: 10.1063/1.4993985
[16]
Meel K, Mahala P, Singh S. Design and fabrication of multi quantum well based GaN/InGaN blue LED. IOP Conf Ser: Mater Sci Eng, 2018, 331, 012008 doi: 10.1088/1757-899X/331/1/012008
[17]
Gautier S, Patriarche G, Moudakir T. Deep structural analysis of novel BGaN material layers grown by MOVPE. J Cryst Growth 2011, 315, 288 doi: 10.1016/j.jcrysgro.2010.08.042
[18]
Pease R S. An X-ray study of boron nitride. Acta Crystallogr. 1952, 5, 356. doi: 10.1107/S0365110X52001064
[19]
Herold A, Marzluf B, Perio P, et al. Inorganic reactions and methods. Formation of Ceramics Seances Acad Sci 1958, 246, 1866
[20]
Thomas J, Weston N E, O’connor T, et al. Boron nitride, thermal transformation to ordered-layer-lattice boron nitride. J Am Chem Soc 1962, 84, 4619. doi: 10.1021/ja00883a001
[21]
Wentorf R Jr. Cubic form of boron nitride. J Chem Phys, 1957, 26, 956. doi: 10.1063/1.1745964
[22]
Wentorf R Jr. Synthesis of the cubic form of boron nitride. J Chem Phys. 1961, 34, 809. doi: 10.1063/1.1731679
[23]
Tsao J Y, Chowdhury S, Hollis M A, et al. Ultrawide-bandgap semiconductors: research opportunities and challenges. J Adv Electron Mater. 2018, 4, 1600501 doi: 10.1002/aelm.201600501
[24]
Zhang X. Thin solid films electronic and photonic applications, 2013, 544, 2. doi: 10.1016/j.tsf.2013.07.001
[25]
Dreyer C E, Lyons J L, Janotti A, et al. Band alignments and polarization properties of BN polymorphs. Appl Phys Express, 2014, 7, 031001. doi: 10.7567/APEX.7.031001
[26]
Gunning B P, Moseley M W, Koleske D D, et al. Phase degradation in BxGa1-xN films grown at low temperature by metalorganic vapor phase epitaxy. J Cryst Growth, 2017, 464, 190. doi: 10.1016/j.jcrysgro.2016.10.054
[27]
Ougazzaden A, Gautier S, Moudakir T. Band gap bowing in BGaN thin films. Appl Phys Lett, 2008, 93, 083118 doi: 10.1063/1.2977588
[28]
Atlas User’s Manual; Silvaco International Inc. Santa Clara, CA, USA. Version: 2012
[29]
Lachebi A, Abid H, DrizMand Al-Douri Y. First-principles study of cubic BxGa1–xN alloys. Int J Nanoelectron, 2008, 1, 81 doi: 10.3906/.z-0902-3
[30]
Schubert E F. Light-emitting diodes. 2nd ed. Cambridge University Press, 2006, 432
[31]
Ambacher O, Dimitrov R, Stutzmann M, et al. Role of spontaneous and piezoelectric polarization induced effects in group-III nitride based heterostructures and devices. J Phys Stat Sol, 1999, 216, 381 doi: 10.1002/(ISSN)1521-3951
Fig. 1.  (Color online) Schematic structure of UV LEDs with GaN and BGaN single quantum well.

Fig. 2.  (Color online) Injection current versus forward voltage for GaN-LED and BGaN-LED.

Fig. 3.  (Color online) Spontaneous emission of GaN-LED and BGaN-LED.

Fig. 4.  (Color online) Power spectral density of GaN-LED and BGaN-LED.

Fig. 5.  (Color online) Light output power of GaN-LED and BGaN-LED.

Fig. 6.  (Color online) Flux spectral density for GaN-LED and BGaN-LED.

Fig. 7.  (Color online) Gain TE for GaN-LED and BGaN-LED.

Fig. 8.  (Color online) External quantum efficiency for GaN-LED and BGaN-LED.

Table 1.   Summarized values of spontaneous emission for GaN-LED and BGaN-LED.

QW thickness (nm) 7 10 15 20
GaN-LED Peak energy (eV) 3.43 3.43 3.44 3.45
λ (nm) 361.5 361.5 360.5 359.4
Spontaneous emission (1028 s?1 cm?3 eV?1) 1.15 1.53 2.36 3.34
BGaN-LED Peak energy (eV) 3.43 3.36 3.36 3.36
λ (nm) 361.5 369 369 369
Spontaneous emission (1028 s?1 cm?3 eV?1) 2.04 3.43 2.53 2.08
Ratio of spontaneous emissions 1.77 2.24 1.07 0.62
Difference between spontaneous emissions (1028 s?1 cm?3 eV?1) 0.89 1.9 0.17 ?1.26
DownLoad: CSV

Table 2.   Summarized values of power spectral density for GaN-LED and BGaN-LED.

QW thickness (nm) 7 10 15 20
GaN-LED Peak energy (eV) 3.46 3.45 3.45 3.45
λ (nm) 358.4 359.4 359.4 359.4
Power spectral density (W cm?1 eV?1) 1.61 1.81 1.84 1.93
BGaN-LED Peak energy (eV) 3.35 3.31 3.31 3.31
λ (nm) 370.1 374.6 374.6 374.6
Power spectral density (W cm?1 eV?1) 2.4 5.6 6.1 6.7
Ratio of power spectral densities 1.49 3.09 3.31 3.47
Difference between power spectral densities (W cm?1 eV?1) 0.79 3.79 4.26 4.77
DownLoad: CSV

Table 3.   Summarized values of flux spectral density for GaN-LED and BGaN-LED.

QW thickness (nm) 7 10 15 20
GaN-LED Peak energy (eV) 3.47 3.46 3.45 3.45
λ (nm) 357.3 358.4 359.4 359.4
Flux spectral density (1018 s?1 cm?1 eV?1) 2.91 3.25 3.32 3.5
BGaN-LED Peak energy (eV) 3.35 3.31 3.31 3.31
λ (nm) 370.1 374.6 374.6 374.6
Flux spectral density (1018 s?1 cm?1 eV?1) 4.48 10.3 11.3 12.5
Ratio of flux spectral densities (s?1 cm?1 eV?1) 1.54 3.17 3.40 3.57
Difference between flux spectral densities (1018 s?1 cm?1 eV?1) 1.57 7.05 7.98 9
DownLoad: CSV
[1]
Hamdoune A. Elaboration du nitrure de gallium, étude de ses propriétés et applications. Thesis of Doctorate, University of Abou-Bakr Belkaid, Tlemcen, Algeria, 2006
[2]
Nakamura S. III-V nitride based light-emitting devices. Solid State Communications, 1997. 102: 237 doi: 10.1016/S0038-1098(96)00722-3
[3]
Masui H, Nakamura S, DenBaars S P, et al. Nonpolar and semipolar III-nitride light-emitting diodes: achievements and challenges. IEEE Trans Electron Devices, 2010, 57: 88 doi: 10.1109/TED.2009.2033773
[4]
Hu H P, Zhou S J, Liu X T, et al. Effects of GaN/AlGaN/sputtered AlN nucleation layers on performance of GaN-based ultraviolet light-emitting diodes. J Scientific Reports, 2017, 7, 44627 doi: 10.1038/srep44627
[5]
Kneissl M, Kolbe T, Chua C, et al. Advances in group III-nitride-based deep UV light-emitting diode technology. J Semicond Sci Technol 2011, 26 , 014036 doi: 10.1088/0268-1242/26/1/014036
[6]
Kneissl M, Rass J. III nitride ultraviolet emitters. Springer Series in Materials Science 2016, 227, 1
[7]
Khan A, Balakrishnan K, Katona T. Ultraviolet light-emitting diodes based on group three nitrides. J Nat Photonics 2008, 2, 77 doi: 10.1038/nphoton.2007.293
[8]
Nakamura S, Krames M R. History of gallium-nitride-based light-emitting diodes for illumination. Proc IEEE, 2013, 101(10), 2211 doi: 10.1109/JPROC.2013.2274929
[9]
Verzellesi G , Saguatti D, Meneghini M, et al. Efficiency droop in InGaN/GaN blue light-emitting diodes: physic mechanisms remedies. J Appl Phys 2013, 114(7), 071101. doi: 10.1063/1.4816434
[10]
Yang W, Wang W, Lin Y, et al. Deposition of nonpolar mplane InGaN/GaN multiple quantum wells on LiGaO+(100) substrates. J Mater Chem C 2014, 2(5), 801 doi: 10.1039/C3TC31935K
[11]
Schubert M F, Xu J, Kim J K, et al. Polarization-matched GaInN/AlGaInN multi-quantum-well light-emitting diodes with reduced efficiency droop. Appl Phys Lett. 2008, 93(4), 041102. doi: 10.1063/1.2963029
[12]
Lin Z T, Wang H Y, Wang W L, et al. Employing low-temperature barriers to achieve strain-relaxed and high-performance GaN-based LEDs. J Opt Express, 2016, 24, 11886. doi: 10.1364/OE.24.011885
[13]
Hirayama H, Fujikawa S, Noguchi N, et al. 222–282 nm AlGaN and InAlGaN-based deep-UV LEDs fabricated on high-quality AlN on sapphire. J Phys Status Solidi A, 2009, 206, 1176 doi: 10.1002/pssa.v206:6
[14]
Takano T, Fujikawa S, Kondo Y, et al. Remarkable improvement in output power for an InAlGaN based ultraviolet LED by improving the crystalline quality of AlN/AlGaN templates. J Phys Status Solidi C, 2008, 5, 2102 doi: 10.1002/(ISSN)1610-1642
[15]
Lin Z T, Wang H T, Lin Y H, et al. Stress management on underlying GaN-based epitaxial films: A new vision for achieving high-performance LEDs on Si substrates. J Appl Phys, 2017, 122, 204503. doi: 10.1063/1.4993985
[16]
Meel K, Mahala P, Singh S. Design and fabrication of multi quantum well based GaN/InGaN blue LED. IOP Conf Ser: Mater Sci Eng, 2018, 331, 012008 doi: 10.1088/1757-899X/331/1/012008
[17]
Gautier S, Patriarche G, Moudakir T. Deep structural analysis of novel BGaN material layers grown by MOVPE. J Cryst Growth 2011, 315, 288 doi: 10.1016/j.jcrysgro.2010.08.042
[18]
Pease R S. An X-ray study of boron nitride. Acta Crystallogr. 1952, 5, 356. doi: 10.1107/S0365110X52001064
[19]
Herold A, Marzluf B, Perio P, et al. Inorganic reactions and methods. Formation of Ceramics Seances Acad Sci 1958, 246, 1866
[20]
Thomas J, Weston N E, O’connor T, et al. Boron nitride, thermal transformation to ordered-layer-lattice boron nitride. J Am Chem Soc 1962, 84, 4619. doi: 10.1021/ja00883a001
[21]
Wentorf R Jr. Cubic form of boron nitride. J Chem Phys, 1957, 26, 956. doi: 10.1063/1.1745964
[22]
Wentorf R Jr. Synthesis of the cubic form of boron nitride. J Chem Phys. 1961, 34, 809. doi: 10.1063/1.1731679
[23]
Tsao J Y, Chowdhury S, Hollis M A, et al. Ultrawide-bandgap semiconductors: research opportunities and challenges. J Adv Electron Mater. 2018, 4, 1600501 doi: 10.1002/aelm.201600501
[24]
Zhang X. Thin solid films electronic and photonic applications, 2013, 544, 2. doi: 10.1016/j.tsf.2013.07.001
[25]
Dreyer C E, Lyons J L, Janotti A, et al. Band alignments and polarization properties of BN polymorphs. Appl Phys Express, 2014, 7, 031001. doi: 10.7567/APEX.7.031001
[26]
Gunning B P, Moseley M W, Koleske D D, et al. Phase degradation in BxGa1-xN films grown at low temperature by metalorganic vapor phase epitaxy. J Cryst Growth, 2017, 464, 190. doi: 10.1016/j.jcrysgro.2016.10.054
[27]
Ougazzaden A, Gautier S, Moudakir T. Band gap bowing in BGaN thin films. Appl Phys Lett, 2008, 93, 083118 doi: 10.1063/1.2977588
[28]
Atlas User’s Manual; Silvaco International Inc. Santa Clara, CA, USA. Version: 2012
[29]
Lachebi A, Abid H, DrizMand Al-Douri Y. First-principles study of cubic BxGa1–xN alloys. Int J Nanoelectron, 2008, 1, 81 doi: 10.3906/.z-0902-3
[30]
Schubert E F. Light-emitting diodes. 2nd ed. Cambridge University Press, 2006, 432
[31]
Ambacher O, Dimitrov R, Stutzmann M, et al. Role of spontaneous and piezoelectric polarization induced effects in group-III nitride based heterostructures and devices. J Phys Stat Sol, 1999, 216, 381 doi: 10.1002/(ISSN)1521-3951
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    Received: 04 May 2018 Revised: 08 June 2018 Online: Accepted Manuscript: 11 January 2019Uncorrected proof: 11 January 2019Published: 01 March 2019

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      Asma Belaid, Abdelkader Hamdoune. Numerical simulation of UV LEDs with GaN and BGaN single quantum well[J]. Journal of Semiconductors, 2019, 40(3): 032802. doi: 10.1088/1674-4926/40/3/032802 ****A Belaid, A Hamdoune, Numerical simulation of UV LEDs with GaN and BGaN single quantum well[J]. J. Semicond., 2019, 40(3): 032802. doi: 10.1088/1674-4926/40/3/032802.
      Citation:
      Asma Belaid, Abdelkader Hamdoune. Numerical simulation of UV LEDs with GaN and BGaN single quantum well[J]. Journal of Semiconductors, 2019, 40(3): 032802. doi: 10.1088/1674-4926/40/3/032802 ****
      A Belaid, A Hamdoune, Numerical simulation of UV LEDs with GaN and BGaN single quantum well[J]. J. Semicond., 2019, 40(3): 032802. doi: 10.1088/1674-4926/40/3/032802.

      Numerical simulation of UV LEDs with GaN and BGaN single quantum well

      DOI: 10.1088/1674-4926/40/3/032802
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      • Corresponding author: Email: belaidaasma@gmail.com
      • Received Date: 2018-05-04
      • Revised Date: 2018-06-08
      • Published Date: 2019-03-01

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